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Photothermal materials for efficient solar powered steam generation

Fenghua Liu, Yijian Lai, Binyuan Zhao, Robert Bradley, Weiping Wu

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 636-653 doi: 10.1007/s11705-019-1824-1

摘要： Solar powered steam generation is an emerging area in the field of energy harvest and sustainable technologies. The nano-structured photothermal materials are able to harvest energy from the full solar spectrum and convert it to heat with high efficiency. Moreover, the materials and structures for heat management as well as the mass transportation are also brought to the forefront. Several groups have reported their materials and structures as solutions for high performance devices, a few creatively coupled other physical fields with solar energy to achieve even better results. This paper provides a systematic review on the recent developments in photothermal nanomaterial discovery, material selection, structural design and mass/heat management, as well as their applications in seawater desalination and fresh water production from waste water with free solar energy. It also discusses current technical challenges and likely future developments. This article will help to stimulate novel ideas and new designs for the photothermal materials, towards efficient, low cost practical solar-driven clean water production.

关键词： solar stream generation     plasmonics     porous carbon     photothermal materials     solar energy conversion efficiency     water vapor generation rate    

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Facile strategy for carbon foam fabrication with lignin as sole feedstock and its applications

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1051-1064 doi: 10.1007/s11705-022-2248-x

摘要： This research is a follow-up to our recent discovery of a facile strategy for directly converting lignin powder into carbon foam. In this work, we report that the thermal pretreatment parameters in air can remarkably influence the formation and properties of the derived carbon foam. Thermal pretreatment parameters (heating rate, temperature, and residence time) were systematically investigated and a conversion mechanism into carbon foam was proposed. During the thermal pretreatment, relatively low temperatures, low heating rates, and short residence time hindered the formation of smooth and well-connected structures in the carbon foam. The overall product yields were similar regardless of the thermal pretreatment conditions. The densities of the different carbon foams ranged 0.27–0.83 g∙cm−3. The carbon foams with the highest compressive strengths (> 10 MPa) were KLPC280-2-5, KLPC300-0-5, and KLPC300-2-2.5. KLPC280-2-5 exhibited a high iodine sorption value (182 mg∙g−1). KLPC300-2-5 exhibited a specific capacitance of 158 F∙g−1 at a current density of 0.05 A∙g−1. The maximum evaporation rates in the solar vapor generation experiments were 1.05 and 1.38 kg∙m−2∙h−1 under 100 and 150 mW∙cm−2 irradiation, respectively. The good performances are attributed to the robust, porous, and continuous structure.

关键词： lignin     carbon foam     thermal pretreatment     solar vapor generation    

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Performance of a bi-layer solar steam generation system working at a high-temperature of top surface

Jinxin ZHONG, Congliang HUANG

《能源前沿（英文）》 2023年 第17卷 第1期   页码 141-148 doi: 10.1007/s11708-021-0725-4

摘要： Many efforts have been focused on enhancing the vapor generation in bi-layer solar steam generation systems for obtaining as much pure water as possible. However, the methods to enhance the vapor temperature is seldom studied although the high-temperature vapor has a wide use in medical sterilization and electricity generation. In this work, to probe the high-temperature vapor system, an improved macroscopic heat and mass transfer model was proposed. Then, using the finite element method to solve the model, the influences of some main factors on the evaporation efficiency and vapor temperature were discussed, including effects of the vapor transport conditions and the heat dissipation conditions. The results show that the high-temperature vapor could not be obtained by enhancing the heat-insulating property of the bi-layer systems but by applying the optimal porosity and proper absorbers. This paper is expected to provide some information for designing a bi-layered system to produce high-temperature vapor.

关键词： solar steam generation     solar energy     numerical method     porous material    

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Impacts of solar multiple on the performance of direct steam generation solar power tower plant with

Yan LUO, Xiaoze DU, Lijun YANG, Chao XU, Muhammad AMJAD

《能源前沿（英文）》 2017年 第11卷 第4期   页码 461-471 doi: 10.1007/s11708-017-0503-5

摘要： Solar multiple (SM) and thermal storage capacity are two key design parameters for revealing the performance of direct steam generation (DSG) solar power tower plant. In the case of settled land area, SM and thermal storage capacity can be optimized to obtain the minimum levelized cost of electricity (LCOE) by adjusting the power generation output. Taking the dual-receiver DSG solar power tower plant with a given size of solar field equivalent electricity of 100 MW in Sevilla as a reference case, the minimum LCOE is 21.77 ￠/kWh with an SM of 1.7 and a thermal storage capacity of 3 h. Besides Sevilla, two other sites are also introduced to discuss the influence of annual DNI. When compared with the case of Sevilla, the minimum LCOE and optimal SM of the San Jose site change just slightly, while the minimum LCOE of the Bishop site decreases by 32.8% and the optimal SM is reduced to 1.3. The influence of the size of solar field equivalent electricity is studied as well. The minimum LCOE decreases with the size of solar field, while the optimal SM and thermal storage capacity still remain unchanged. In addition, the sensitivity of different investment in sub-system is investigated. In terms of optimal SM and thermal storage capacity, they can decrease with the cost of thermal storage system but increase with the cost of power generation unit.

关键词： direct steam generation     solar power tower     solar multiple     thermal energy storage capacity     levelized cost of electricity (LCOE)    

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Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

《能源前沿（英文）》 2023年 第17卷 第1期   页码 16-42 doi: 10.1007/s11708-023-0866-8

摘要： To reduce the levelized cost of energy for concentrating solar power (CSP), the outlet temperature of the solar receiver needs to be higher than 700 °C in the next-generation CSP. Because of extensive engineering application experience, the liquid-based receiver is an attractive receiver technology for the next-generation CSP. This review is focused on four of the most promising liquid-based receivers, including chloride salts, sodium, lead-bismuth, and tin receivers. The challenges of these receivers and corresponding solutions are comprehensively reviewed and classified. It is concluded that combining salt purification and anti-corrosion receiver materials is promising to tackle the corrosion problems of chloride salts at high temperatures. In addition, reducing energy losses of the receiver from sources and during propagation is the most effective way to improve the receiver efficiency. Moreover, resolving the sodium fire risk and material compatibility issues could promote the potential application of liquid-metal receivers. Furthermore, using multiple heat transfer fluids in one system is also a promising way for the next-generation CSP. For example, the liquid sodium is used as the heat transfer fluid while the molten chloride salt is used as the storage medium. In the end, suggestions for future studies are proposed to bridge the research gaps for > 700 °C liquid-based receivers.

关键词： next-generation concentrating solar power     liquid-based solar receiver     molten salt     liquid metals    

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Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunctionsolar cells at high pressure and high power

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

《能源前沿（英文）》 2017年 第11卷 第1期   页码 85-91 doi: 10.1007/s11708-016-0437-3

摘要： The intrinsic a-Si:H passivation layer inserted between the doped a-Si:H layer and the c-Si substrate is very crucial for improving the performance of the a-Si:H/c-Si heterojunction (SHJ) solar cell. The passivation performance of the a-Si:H layer is strongly dependent on its microstructure. Usually, the compact a-Si:H deposited near the transition from the amorphous phase to the nanocrystalline phase by plasma enhanced chemical vapor deposition (PECVD) can provide excellent passivation. However, at the low deposition pressure and low deposition power, such an a-Si:H layer can be only prepared in a narrow region. The deposition condition must be controlled very carefully. In this paper, intrinsic a-Si:H layers were prepared on n-type Cz c-Si substrates by 27.12 MHz PECVD at a high deposition pressure and high deposition power. The corresponding passivation performance on c-Si was investigated by minority carrier lifetime measurement. It was found that an excellent a-Si:H passivation layer could be obtained in a very wide deposition pressure and power region. Such wide process window would be very beneficial for improving the uniformity and the yield for the solar cell fabrication. The a-Si:H layer microstructure was further investigated by Raman and Fourier transform infrared (FTIR) spectroscopy characterization. The correlation between the microstructure and the passivation performance was revealed. According to the above findings, the a-Si:H passivation performance was optimized more elaborately. Finally, a large-area SHJ solar cell with an efficiency of 22.25% was fabricated on the commercial 156 mm pseudo-square n-type Cz c-Si substrate with the open-circuit voltage ( ) of up to 0.732 V.

关键词： PECVD     high pressure and high power     a-Si:H microstructure     passivation     heterojunction solar cell    

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Emerging technologies to power next generation mobile electronic devices using solar energy

Dewei JIA , Yubo DUAN , Jing LIU ,

《能源前沿（英文）》 2009年 第3卷 第3期   页码 262-288 doi: 10.1007/s11708-009-0015-z

摘要： Mobile electronic devices such as MP3, mobile phones, and wearable or implanted medical devices have already or will soon become a necessity in peoples’ lives. However, the further development of these devices is restricted not only by the inconvenient charging process of the power module, but also by the soaring prices of fossil fuel and its downstream chain of electricity manipulation. In view of the huge amount of solar energy fueling the world biochemically and thermally, a carry-on electricity harvester embedded in portable devices is emerging as a most noteworthy research area and engineering practice for a cost efficient solution. Such a parasitic problem is intrinsic in the next generation portable devices. This paper is dedicated to presenting an overview of the photovoltaic strategy in the chain as a reference for researchers and practitioners committed to solving the problem.

关键词： photovoltaic conversion     energy harvesting     solar cell     maximum power point track algorithm     PV electricity storage     mobile/standalone PV application    

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Efficient use of waste heat and solar energy: Technologies of cooling, heating, power generation and

Ya-Ling HE, Ruzhu WANG, Anthony Paul ROSKILLY, Peiwen LI

《能源前沿（英文）》 2017年 第11卷 第4期   页码 411-413 doi: 10.1007/s11708-017-0525-z

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Technological development of multi-energy complementary system based on solar PVs and MGT

Xiaojing LV, Yu WENG, Xiaoyi DING, Shilie WENG, Yiwu WENG

《能源前沿（英文）》 2018年 第12卷 第4期   页码 509-517 doi: 10.1007/s11708-018-0598-3

摘要：

The complementary micro-energy network system consisting of solar photovoltaic power generation (solar PVs) and micro-gas turbine (MGT), which not only improves the absorption rate and reliability of photovoltaic power, but also has the advantages of low emission, high efficiency, and good fuel adaptability, has become one of the most promising distributed power systems in the field of micro grid. According to the development of current technology and the demand of actual work, this research described the domestic and foreign development of micro-energy network system based on solar PVs and MGT. Moreover, it analyzed the challenges and future development regarding the micro-energy network system in planning and design, energy utilization optimization and dispatching management, and system maintenance, respectively. Furthermore, it predicted the future development of the key technology of the multi-energy complementary system. These results will be beneficial for the progress of this field both in theory and practice.

关键词： renewable energy     solar photovoltaic power generation     micro gas turbine     multi-energy complementary system     micro-energy network    

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Heat transfer characteristics of high heat flux vapor chamber

Dongchuan MO, Shushen LU, Haoliang ZHENG, Chite CHIN,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 166-170 doi: 10.1007/s11708-009-0076-z

摘要： To meet the challenge of heat spreading in electronic products, highly efficient high heat flux heat transfer vapor chambers have been manufactured and their heat transfer characteristics have been studied by a fast test system. A solid copper block with the same shape as the vapor chamber is used to compare the performance of the vapor chamber. The result shows that, it will take about 5min to achieve a steady state in the fast test system. The heat transfer characteristics of the vapor chamber are more superior to those of the copper block. In this paper, total thermal resistance of the test system is used to evaluate the heat transfer characteristics of the vapor chamber, because it has already been used to consider both the spreading thermal resistance and the flatness of the vapor chamber.

关键词： high heat flux     vapor chamber (VC)     heat transfer characteristics     fast test    

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New refrigeration system using CO vapor-solid as refrigerant

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年 第2卷 第4期   页码 494-498 doi: 10.1007/s11708-008-0070-x

摘要： A refrigerant must be in the vapor-liquid phase in a vapor-compression refrigeration system, therefore, CO cannot be used as a refrigerant for temperatures lower than -56°C because solid CO will form under the triple point temperature of -56°C. A refrigeration system with CO vapor-solid particles as refrigerant is put forward, by which a temperature lower than the triple point is achieved. An adjustable nozzle, a sublimator, a high-pressure regulating valve and a low-pressure regulating valve are used to replace the conventional evaporator. Theoretical cycle analysis of the refrigeration system shows that its COP can be 50% higher than that of the conventional one.

关键词： refrigerant     adjustable     temperature     vapor-compression refrigeration     sublimator    

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Modeling of coal swelling induced by water vapor adsorption

Zhejun PAN

《化学科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 94-103 doi: 10.1007/s11705-011-1172-2

摘要： Gas adsorption-induced coal swelling is a well-know phenomenon. Coal swelling or shrinkage by adsorption or desorption of water vapor has not been well understood but has significant implications on gas drainage process for underground coal mining and for primary and enhanced coalbed methane production. Decreased matrix moisture content leads to coal shrinkage and thus the change of cleat porosity and permeability under reservoir conditions. Unlike gas adsorption in coal which usually forms a single layer of adsorbed molecules, water vapor adsorption in the coal micropores forms multilayer of adsorbed molecules. In this work, a model has been developed to describe the coal swelling strain with respect to the amount of moisture intake by the coal matrix. The model extended an energy balance approach for gas adsorption-induced coal swelling to water vapor adsorption-induced coal swelling, assuming that only the first layer of adsorbed molecules of the multilayer adsorption changes the surface energy, which thus causes coal to swell. The model is applied to describe the experimental swelling strain data measured on an Australian coal. The results show good agreement between the model and the experimental data.

关键词： multilayer adsorption     vapour pressure     coal shrinkage     relative humidity     permeability    

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Effects of BTA2 as the third component on the charge carrier generation and recombination behavior of

Leijing Liu, Hao Zhang, Bo Xiao, Yang Liu, Bin Xu, Chen Wang, Shanpeng Wen, Erjun Zhou, Gang Chen, Chan Im, Wenjing Tian

《化学科学与工程前沿（英文）》 2021年 第15卷 第1期   页码 127-137 doi: 10.1007/s11705-020-1936-7

摘要： Effects of a benzotriazole (BTA)-based small molecule, BTA2, as the third component on the charge carrier generation and recombination behavior of poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7):[6,6]-phenyl-C -butyric acid methyl ester (PC BM) organic solar cells (OSCs) were investigated by optical simulation of a transfer matrix model (TMM), photo-induced charge extraction by linearly increasing voltage (photo-CELIV) technique, atomic force microscope (AFM), and the Onsager–Braun model analysis. BTA2 is an A A D A A -type non-fullerene small molecule with thiazolidine-2,4-dione, BTA, and indacenodithiophene as the terminal acceptor (A ), bridge acceptor (A ), and central donor (D), respectively. The short-circuit current density of the OSCs with BTA2 can be enhanced significantly owing to a complementary absorption spectrum. The optical simulation of TMM shows that the ternary OSCs exhibit higher internal absorption than the traditional binary OSCs without BTA2, resulting in more photogenerated excitons in the ternary OSCs. The photo-CELIV investigation indicates that the ternary OSCs suffer higher charge trap-limited bimolecular recombination than the binary OSCs. AFM images show that BTA2 aggravates the phase separation between the donor and the acceptor, which is disadvantageous to charge carrier transport. The Onsager-Braun model analysis confirms that despite the charge collection efficiency of the ternary OSCs being lower than that of the binary OSCs, the optimized photon absorption and exciton generation processes of the ternary OSCs achieve an increase in photogenerated current and thus improve power conversion efficiency.

关键词： third component     organic solar cells     charge carrier generation     charge carrier recombination     bimolecular recombination    

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太阳能光伏发电

2022年12月14日

关键词： 2022全球十大工程成就    

标题 作者 时间 类型 操作

Photothermal materials for efficient solar powered steam generation

Fenghua Liu, Yijian Lai, Binyuan Zhao, Robert Bradley, Weiping Wu

期刊论文

Facile strategy for carbon foam fabrication with lignin as sole feedstock and its applications

期刊论文

Performance of a bi-layer solar steam generation system working at a high-temperature of top surface

Jinxin ZHONG, Congliang HUANG

期刊论文

Impacts of solar multiple on the performance of direct steam generation solar power tower plant with

Yan LUO, Xiaoze DU, Lijun YANG, Chao XU, Muhammad AMJAD

期刊论文

Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

期刊论文

Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunctionsolar cells at high pressure and high power

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

期刊论文

Emerging technologies to power next generation mobile electronic devices using solar energy

Dewei JIA , Yubo DUAN , Jing LIU ,

期刊论文

Efficient use of waste heat and solar energy: Technologies of cooling, heating, power generation and

Ya-Ling HE, Ruzhu WANG, Anthony Paul ROSKILLY, Peiwen LI

期刊论文

Technological development of multi-energy complementary system based on solar PVs and MGT

Xiaojing LV, Yu WENG, Xiaoyi DING, Shilie WENG, Yiwu WENG

期刊论文

Heat transfer characteristics of high heat flux vapor chamber

Dongchuan MO, Shushen LU, Haoliang ZHENG, Chite CHIN,

期刊论文

New refrigeration system using CO vapor-solid as refrigerant

HUANG Dongping, DING Guoliang, QUACK Hans

期刊论文

Modeling of coal swelling induced by water vapor adsorption

Zhejun PAN

期刊论文

Effects of BTA2 as the third component on the charge carrier generation and recombination behavior of

Leijing Liu, Hao Zhang, Bo Xiao, Yang Liu, Bin Xu, Chen Wang, Shanpeng Wen, Erjun Zhou, Gang Chen, Chan Im, Wenjing Tian

期刊论文

太阳能光伏发电

2022年12月14日

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太阳能光伏发电（英文）

2022年12月20日

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